Main group metal chemistry: Reaction of potassium germabenzenide with benzil: Unusual ring opening to form a unique polycyclic penta-coordinated germanate

Tsuji, Shingo; Nishino, Ryohei; Tokitoh, Norihiro; Yamada, Hiroko; Mizuhata, Yoshiyuki

Creator: Tsuji, Shingo Nishino, Ryohei Tokitoh, Norihiro Yamada, Hiroko Mizuhata, Yoshiyuki Publication: Berlin: de Gruyter, 2024
URN: urn:nbn:de:101:1-2407281541497.078469587940

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Path:: Reaction of potassium germabenzenide with benzil: Unusual ring opening to form a unique polycyclic penta-coordinated germanate

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Main group metal chemistry

Periodical

Title:: Main group metal chemistry

Publication:: Berlin: de Gruyter

Note:: Gesehen am 22.07.21; Fortsetzung der Druck-Ausgabe; Open Access; Namensnennung 4.0 International; C!URL gelöscht(01-02-12)

Scope:: Online-Ressource

ISSN:: 2191-0219

ZDB-ID:: 2602433-0

VÖBB-Katalog:: 15605267

Keywords:: Zeitschrift

Classification:: Technik

Collection:: Technik

Copyright:: Rights reserved

Accessibility:: Free Access

Title:: Main group metal chemistry

Publication:: Berlin: de Gruyter

Note:: Gesehen am 22.07.21; Fortsetzung der Druck-Ausgabe; Open Access; Namensnennung 4.0 International; C!URL gelöscht(01-02-12)

Scope:: Online-Ressource

ISSN:: 2191-0219

ZDB-ID:: 2602433-0

VÖBB-Katalog:: 15605267

Keywords:: Zeitschrift

Classification:: Technik

Collection:: Technik

Copyright:: Rights reserved

Accessibility:: Free Access

Reaction of potassium germabenzenide with benzil: Unusual ring opening to form a unique polycyclic penta-coordinated germanate

Article

Author:: Tsuji, Shingo; Nishino, Ryohei; Tokitoh, Norihiro; Yamada, Hiroko; Mizuhata, Yoshiyuki

Title:: Reaction of potassium germabenzenide with benzil: Unusual ring opening to form a unique polycyclic penta-coordinated germanate

Publication:: Berlin: de Gruyter, 2024

Language:: English

Information:: Abstract: The reaction of potassium 2-t-Bu-germabenzenide, in which the anionic carbon atom of phenyl anion is replaced with a germanium atom, with benzil resulted in the 1:2 reaction to give a unique penta-coordinated germanate having a 1,3,2-dioxagermole skeleton. This clearly reflects the characteristics of the germabenzenide as a divalent germanium species.

Scope:: Online-Ressource

Note:: Open Access; Archivierung/Langzeitarchivierung gewährleistet

Keywords:: germanium ; germanate ; germabenzenide

Classification:: Technik; Sonstiges

URN:: urn:nbn:de:101:1-2407281541497.078469587940

Collection:: Technik; Sonstiges

Copyright:: CC BY

Accessibility:: Free Access

Author:: Tsuji, Shingo; Nishino, Ryohei; Tokitoh, Norihiro; Yamada, Hiroko; Mizuhata, Yoshiyuki

Title:: Reaction of potassium germabenzenide with benzil: Unusual ring opening to form a unique polycyclic penta-coordinated germanate

Publication:: Berlin: de Gruyter, 2024

Language:: English

Information:: Abstract: The reaction of potassium 2-t-Bu-germabenzenide, in which the anionic carbon atom of phenyl anion is replaced with a germanium atom, with benzil resulted in the 1:2 reaction to give a unique penta-coordinated germanate having a 1,3,2-dioxagermole skeleton. This clearly reflects the characteristics of the germabenzenide as a divalent germanium species.

Scope:: Online-Ressource

Note:: Open Access; Archivierung/Langzeitarchivierung gewährleistet

Keywords:: germanium ; germanate ; germabenzenide

Classification:: Technik; Sonstiges

URN:: urn:nbn:de:101:1-2407281541497.078469587940

Collection:: Technik; Sonstiges

Copyright:: CC BY

Accessibility:: Free Access

Reaction of potassium germabenzenide with benzil: Unusual ring opening to form a unique polycyclic penta-coordinated germanate / Tsuji, Shingo (CC BY)